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Synthesis of the heterocyclic core of the D-series GE2270

A straightforward enantiomerically pure synthesis of the heterocyclic core of the D-series GE2270 is reported. The synthetic strategy combines the Hantzsch thiazole’s building condensation with a cross-coupling reaction including direct C–H hetarylation to build and connect step-by-step thiazolyl mo...

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Gardado en:
Principais autores: Christophe Berini, Thibaut Martin, Pierrik Lassalas, Francis Marsais, Christine Baudequin, Christophe Hoarau
Formato: Artigo
Idioma:Inglês
Publicado: Beilstein-Institut 2017-07-01
Series:Beilstein Journal of Organic Chemistry
Assuntos:
antibiotic
bromination
BSC
C–H arylation
cross-coupling
Hantzsch synthesis
thiopeptide
Acceso en liña:https://doi.org/10.3762/bjoc.13.137
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