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Tricine-supported polyoxo(alkoxo)lanthanide cluster {Ln15} (Ln = Eu, Gd, Tb) with magnetic refrigerant and fluorescent properties

A family of polyoxo(alkoxo)lanthanide cluster {Ln15} (Ln = Eu (1), Gd (2), Tb (3)) was successfully isolated via a simple hydrolysis reaction of lanthanide metal ions in the presence of tricine ligands. X-ray diffraction analyses revealed that {Ln15} displayed a wheel-like structure with a µ5-chlori...

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Principais autores: Peng-Fei Sun, Xiao-Nan Zhang, Cai-Hong Fan, Wei-Peng Chen, Yan-Zhen Zheng
Formato: Artigo
Idioma:Inglês
Publicado em: Tsinghua University Press 2023-06-01
coleção:Polyoxometalates
Assuntos:
polymetallic complexes
lanthanide elements
luminescence
magnetic refrigeration
magnetic exchange
Acesso em linha:https://www.sciopen.com/article/10.26599/POM.2023.9140026
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