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Hierarchically assembled helicates as reaction platform – from stoichiometric Diels–Alder reactions to enamine catalysis

The stereoselectivity of a Diels–Alder reaction within the periphery of hierarchically assembled titanium(IV) helicates formed from mixtures of achiral, reactive and chiral, unreactive ligands was investigated in detail. Following the pathway of the chiral induction, the chiral ligands, solvents as...

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Principais autores: David Van Craen, Jenny Begall, Johannes Großkurth, Leonard Himmel, Oliver Linnenberg, Elisabeth Isaak, Markus Albrecht
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2020-09-01
coleção:Beilstein Journal of Organic Chemistry
Assuntos:
diels–alder reaction
enamine catalysis
hierarchical helicates
remote-control
stereoselectivity
Acesso em linha:https://doi.org/10.3762/bjoc.16.195
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