Chlorine Isotope Effects from Isotope Ratio Mass Spectrometry Suggest Intramolecular C-Cl Bond Competition in Trichloroethene (TCE) Reductive Dehalogenation

Chlorinated ethenes are prevalent groundwater contaminants. To better constrain (bio)chemical reaction mechanisms of reductive dechlorination, the position-specificity of reductive trichloroethene (TCE) dehalogenation was investigated. Selective biotransformation reactions (i) of tetrachloroethene (...

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主要な著者:	Stefan Cretnik, Anat Bernstein, Orfan Shouakar-Stash, Frank Löffler, Martin Elsner
フォーマット:	Artigo
言語:	Inglês
出版事項:	MDPI AG 2014-05-01
シリーズ:	Molecules
主題:	reductive dehalogenation chlorinated ethenes trichloroethene biodegradation organohalide respiration dechlorination mechanism regioselectivity vitamin B12 reductive dehalogenase
オンライン･アクセス:	http://www.mdpi.com/1420-3049/19/5/6450
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