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<b>Vinyltriphenylphosphonium salt-mediated preparation of thiophene-containing electron-poor alkenes from acetylenic esters, 2-thienylmethanol and triphenylphosphine</b>

Protonation of the highly reactive 1:1 intermediates, produced in the reaction between triphenylphosphine and alkyl acetylenecarboxylates (methyl acetylenecarboxylate, ethyl acetylenecarboxylate and ethyl phenylacetylenecarboxylate) by 2-thienylmethanol leads to vinyltriphenylphosphonium salts, whic...

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Detalhes bibliográficos
Principais autores: Nahid Shajari, Ali Ramazani, Yavar Ahmadi
Formato: Artigo
Idioma:Inglês
Publicado em: Chemical Society of Ethiopia 2011-04-01
coleção:Bulletin of the Chemical Society of Ethiopia
Assuntos:
Acesso em linha:http://ajol.info/index.php/bcse/article/view/63370
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