Crystal structure of a Pd4 carbonyl triphenylphosphane cluster [Pd4(CO)5(PPh3)4]·2C4H8O, comparing solvates

Attempts to synthesize Au–Pd heterometallic compounds from homonuclear palladium or gold complexes, [Pd(PtBu2)2] and [Au(PPh3)Cl] in a tetrahydrofuran (THF) solution under a CO atmosphere resulted in a homonuclear Pd cluster, namely pentakis(μ-carbonyl-κ2C:C)tetrakis(triphenylphosphane-κP)tetrapalla...

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Bibliografische Detailangaben

Hauptverfasser:	Koen Robeyns, Christopher Willocq, Bernard Tinant, Michel Devillers, Sophie Hermans
Format:	Artigo
Sprache:	Inglês
Veröffentlicht:	International Union of Crystallography 2016-02-01
Schriftenreihe:	Acta Crystallographica Section E: Crystallographic Communications
Schlagworte:	structure transformation homonuclear cluster palladium gold crystal structure
Online-Zugang:	http://scripts.iucr.org/cgi-bin/paper?S205698901502441X
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