Central-to-Folding Chirality Control: Asymmetric Synthesis of Multilayer 3D Targets With Electron-Deficient Bridges

New multilayer 3D chiral molecules have been designed and synthesized asymmetrically through the strategy of center-to-multilayer folding chirality control and double Suzuki couplings. Individual diastereoisomers were readily obtained and separated via flash column chromatography. The key diastereoi...

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Prif Awduron:	Shengzhou Jin, Jia-Ying Wang, Yao Tang, Hossein Rouh, Sai Zhang, Ting Xu, Yu Wang, Qingkai Yuan, Daixiang Chen, Daniel Unruh, Guigen Li
Fformat:	Artigo
Iaith:	Inglês
Cyhoeddwyd:	Frontiers Media S.A. 2022-03-01
Cyfres:	Frontiers in Chemistry
Pynciau:	multilayer folding chirality asymmetric synthesis asymmetric Suzuki–Miyaura coupling central-to-folding chirality planar packing
Mynediad Ar-lein:	https://www.frontiersin.org/articles/10.3389/fchem.2022.860398/full
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