Chemoenzymatic synthesis of the cardenolide rhodexin A and its aglycone sarmentogenin
Herein, we report a concise chemoenzymatic synthesis of the cardenolide rhodexin A in 9 steps and the first protecting-group-free synthesis of its aglycone sarmentogenin in 7 steps from 17-deoxycortisone. The synthesis features a scalable enzymatic C14–H α-hydroxylation, a Bestmann ylide-enabled one...
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| Автори: | , , , , |
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| Формат: | Artigo |
| Мова: | Inglês |
| Опубліковано: |
Beilstein-Institut
2025-12-01
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| Серія: | Beilstein Journal of Organic Chemistry |
| Предмети: | |
| Онлайн доступ: | https://doi.org/10.3762/bjoc.21.204 |
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