Mononuclear Dysprosium(III) Complexes with Triphenylphosphine Oxide Ligands: Controlling the Coordination Environment and Magnetic Anisotropy

We report the synthesis, structural and magnetic characterization of five mononuclear DyIII ion complexes using triphenylphosphine oxide as a monodentate ligand. They have formulae [DyIII(OPPh3)3(NO3)3] (1), [DyIII(OPPh3)4(NO3)2](NO3) (2), [DyIII(OPPh3)3Cl3] (3), [DyIII(OPPh3)4Cl2]Cl (4) and [DyIII(...

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Autori principali:	Stuart K. Langley, Kuduva R. Vignesh, Kerey Holton, Sophie Benjamin, Gary B. Hix, Wasinee Phonsri, Boujemaa Moubaraki, Keith S. Murray, Gopalan Rajaraman
Natura:	Artigo
Lingua:	Inglês
Pubblicazione:	MDPI AG 2018-06-01
Serie:	Inorganics
Soggetti:	single molecule magnets single ion magnets phosphine oxide complexes lanthanide SMMs magnetic anisotropy ab initio calculations
Accesso online:	http://www.mdpi.com/2304-6740/6/2/61
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