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A Mixed-Valence Tetra-Nuclear Nickel Dithiolene Complex: Synthesis, Crystal Structure, and the Lability of Its Nickel Sulfur Bonds

In this study, by employing a common synthetic protocol, an unusual and unexpected tetra-nuclear nickel dithiolene complex was obtained. The synthesis of the [Ni<sub>4</sub>(ecpdt)<sub>6</sub>]<sup>2−</sup> dianion (ecpdt = (<i>Z</i>)-3-ethoxy-3-oxo-1-phenylprop-1-ene-1,2-bis-thiolate) with two K<su...

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Auteurs principaux: Mohsen Ahmadi, Jevy Correia, Nicolas Chrysochos, Carola Schulzke
Format: Artigo
Langue:Inglês
Publié: MDPI AG 2020-04-01
Collection:Inorganics
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Accès en ligne:https://www.mdpi.com/2304-6740/8/4/27
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