Oxidation of difluorocarbene and subsequent trifluoromethoxylation
Difluorocarbene is a versatile and efficient intermediate for fluorine incorporation. Here, the authors show that difluorocarbene can be oxidized to carbonyl fluoride and this process is confirmed in 18O-trifluoromethoxylation reactions, by observation of AgOCF3 species and theory.
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| Hlavní autoři: | , , , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
Nature Portfolio
2019-11-01
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| Edice: | Nature Communications |
| On-line přístup: | https://doi.org/10.1038/s41467-019-13359-z |
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