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Multi-Centered Solid-Phase Quasi-Intramolecular Redox Reactions of [(Chlorido)Pentaamminecobalt(III)] Permanganate—An Easy Route to Prepare Phase Pure CoMn<sub>2</sub>O<sub>4</sub> Spinel

We synthesized and structurally characterized the previously unknown [Co(NH<sub>3</sub>)<sub>5</sub>Cl](MnO<sub>4</sub>)<sub>2</sub> complex as the precursor of CoMn<sub>2</sub>O<sub>4</sub>. The complex was also deuterated, and its FT-IR, far-IR, low-temperature Raman and UV-VIS spectra were measur...

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Autors principals: Fernanda Paiva Franguelli, Éva Kováts, Zsuzsanna Czégény, Laura Bereczki, Vladimir M. Petruševski, Berta Barta Holló, Kende Attila Béres, Attila Farkas, Imre Miklós Szilágyi, László Kótai
Format: Artigo
Idioma:Inglês
Publicat: MDPI AG 2022-02-01
Col·lecció:Inorganics
Matèries:
permanganate
ammine
quasi-intramolecular redox reaction
cobalt manganite catalyst
spinel
todorokite
Accés en línia:https://www.mdpi.com/2304-6740/10/2/18
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