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Determination of the Very High Barriers to Conformational Processes by the Neat Racemization Technique. Part 1: Barriers to Ring Inversion in Dibenzo [a,c] Dinaphtho [2,3-e; 2,3-g] Cyclooctatetraene and Hindered Rotation in 2,2'-Dimethyl Binaphthyl

A method is described by which it is possible to determine the high barrier to ring inversion and hindered rotation by neat racemization of optically active compounds when the racemization is caused by ring inversion or hindered rotation. The method is based preparation of sufficiently pure enantiom...

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Detalhes bibliográficos
Principais autores: Parviz Rashidi Ranjbar, Jan Sandström, George W. Schriver, Henry N.C. Wong
Formato: Artigo
Idioma:Inglês
Publicado em: Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 1996-06-01
coleção:Iranian Journal of Chemistry & Chemical Engineering
Assuntos:
Acesso em linha:http://www.ijcce.ac.ir/article_10373_2a3304a5c80e6332d6335d6b2f5f40c9.pdf
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