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Revealing the electron driven mechanism in metal catalyzed Kumada cross coupling reaction

Abstract The electron motion mechanism of the metal-catalyzed Kumada cross-coupling reaction, which synthesizes biphenyl from chlorobenzene and phenylmagnesium chloride (a Grignard reagent) using a palladium (Pd) complex with an auxiliary phosphine ligand, is elucidated. This analysis is grounded in...

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Asıl Yazarlar: Noriyuki Takai, Takuro Tsutsumi, Kenichiro Saita, Tetsuya Taketsugu, Takao Tsuneda
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: Nature Portfolio 2025-02-01
Seri Bilgileri:Scientific Reports
Konular:
Cross-coupling reaction
Metal complex reaction
Electronic theory
Grignard reagent
Density functional theory
Orbital energy
Online Erişim:https://doi.org/10.1038/s41598-025-88207-w
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