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Chiral terpene auxiliaries V: Synthesis of new chiral γ-hydroxyphosphine oxides derived from α-pinene

New chiral regioisomeric γ-hydroxyphosphine ligands were synthesized from α-pinene. The key transformation was the thermal [2,3]-sigmatropic rearrangement of allyldiphenylphosphinites, obtained from (1R,2R,4S,5R)-3-methyleneneoisoverbanol and (1R,2R,3R,5R)-4-methyleneneoisopinocampheol, to allylphos...

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Príomhchruthaitheoirí: Anna Kmieciak, Marek P. Krzemiński
Formáid: Artigo
Teanga:Inglês
Foilsithe / Cruthaithe: Beilstein-Institut 2019-10-01
Sraith:Beilstein Journal of Organic Chemistry
Ábhair:
Rochtain ar líne:https://doi.org/10.3762/bjoc.15.242
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