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C-Lactam Derivatives of Oleanolic Acid. Hydrolysis and Further Acylation of Methyl Acetyloleanolate C-Lactam and C-Thiolactam

Acetyl methyl oleanolate was transformed into a seven-membered C-lactam derivative ( 2 ) using Beckmann rearrangement of the corresponding C-oxime during the last step of the synthesis. The C=O group of the lactam system was transformed into a C=S group by Lavesson's reagent. The resulting acetylthi...

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Detalhes bibliográficos
Principais autores: Barbara Bednarczyk–Cwynar, Lucjusz Zaprutko
Formato: Artigo
Idioma:Inglês
Publicado em: SAGE Publishing 2014-03-01
coleção:Natural Product Communications
Acesso em linha:https://doi.org/10.1177/1934578X1400900325
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