Highly stereoselective synthesis of 2-Azabicyclo[3.1.0]hex-3-ene and 5-Azatricyclo[4.1.0.02,4]heptane scaffolds via Rh-catalyzed cyclopropanation of pyrrole

Abstract A rhodium-catalyzed cyclopropanation of pyrrole derivatives with electron-rich cyclopropenes is reported for the efficient access to vinyl functionalized cyclopropane fused pyrrolidine scaffolds, including 2-azabicyclo[3,1,0]hex-3-ene and 5-azatricyclo[4.1.0.02,4]heptane. The method feature...

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Bibliografske podrobnosti

Principais autores:	Dongyan Ju, Chuang Zhao, Bowen Liu, Junming Ma, Shushen Chi, Jinbo Zhao
Format:	Artigo
Jezik:	Inglês
Izdano:	Springer 2026-04-01
Serija:	Journal of Saudi Chemical Society
Teme:	Pyrrole 2-azabicyclo[3.1.0]hex-3-ene Cyclopropanation Rhodium 5-azatricyclo[4.1.0.02,4]heptane
Online dostop:	https://doi.org/10.1007/s44442-026-00075-9
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