Naphtho[1,8-<i>de</i>][1,2]Oxazin-4-ol: Precursor to 1,2,8-Trisubstituted Naphthalenes and 1-Unsubstituted Naphtho[1,2-<i>d</i>]isoxazole 2-Oxide: A Novel Isomerization of the <i>N</i>-Oxide to Nitrile Oxide <i>en Route</i> to Isoxazol(in)es
Naphtho[1,8-<i>de</i>][1,2]oxazin-4-ol and its acyl or benzyl derivatives ring open to various 2,8-dihydroxy-1-naphthonitriles, which, through (de)protection protocols and reduction, afford the target (<i>E</i>)-2-hydroxy-8-methoxy-1-naphthaldehyde. This was converted to its corresponding oxime, whi...
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| Autori principali: | , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
MDPI AG
2023-12-01
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| Serie: | Molecules |
| Soggetti: | |
| Accesso online: | https://www.mdpi.com/1420-3049/29/1/48 |
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