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Studies in Cyclization of Aromatic Epoxy-acyclicpolyprenes: Lewis Superacids and Titanocene Chloride

Two catalytic cascade cyclization methods (radical and cationic) to obtain aromatic polycyclic diterpenes hydroxylated at C3 starting from aromatic epoxypolyprenes were developed. The catalytic use of the Lewis superacid bismuth triflate produces a good yield of cyclized 2 from epoxypolyprene 3 . Th...

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Váldodahkkit: Alexis Castillo, José Fco Quilez del Moral, Alejandro F. Barrero
Materiálatiipa: Artigo
Giella:Inglês
Almmustuhtton: SAGE Publishing 2017-05-01
Ráidu:Natural Product Communications
Liŋkkat:https://doi.org/10.1177/1934578X1701200503
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