Synthesis of bis-spirocyclic derivatives of 3-azabicyclo[3.1.0]hexane via cyclopropene cycloadditions to the stable azomethine ylide derived from Ruhemann's purple

A reliable method for the synthesis of bis-spirocyclic derivatives of 3-azabicyclo[3.1.0]hexanes through the 1,3-dipolar cycloaddition (1,3-DC) reactions of cyclopropenes to the stable azomethine ylide – protonated form of Ruhemann's purple (PRP) has been developed. Both 3-substituted and 3,3-disubs...

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Hlavní autoři:	Alexander S. Filatov, Olesya V. Khoroshilova, Anna G. Larina, Vitali M. Boitsov, Alexander V. Stepakov
Médium:	Artigo
Jazyk:	Inglês
Vydáno:	Beilstein-Institut 2022-06-01
Edice:	Beilstein Journal of Organic Chemistry
Témata:	azomethine ylides cycloaddition cyclopropenes dft calculations spiro heterocycles
On-line přístup:	https://doi.org/10.3762/bjoc.18.77
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