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[Hexaamminecobalt(III)] Dichloride Permanganate—Structural Features and Heat-Induced Transformations into (Co<sup>II</sup>,Mn<sup>II</sup>)(Co<sup>III</sup>,Mn<sup>III</sup>)<sub>2</sub>O<sub>4</sub> Spinels

We synthesized and characterized (IR, Raman, UV, SXRD) hexaamminecobalt(III) dichloride permanganate, [Co(NH<sub>3</sub>)<sub>6</sub>]Cl<sub>2</sub>(MnO<sub>4</sub>) (compound <b>1</b>) as the precursor of Co–Mn–spinel composites with atomic ratios of Co:Mn = 1:1 and 1:3. The 3D−hydrogen bond networ...

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Autori principali: Laura Bereczki, Vladimir M. Petruševski, Fernanda Paiva Franguelli, Kende Attila Béres, Attila Farkas, Berta Barta Holló, Zsuzsanna Czégény, Imre Miklós Szilágyi, László Kótai
Natura: Artigo
Lingua:Inglês
Pubblicazione: MDPI AG 2022-12-01
Serie:Inorganics
Soggetti:
permanganate
ammine
solid-phase quasi-intramolecular redox reaction
todorokite
spinel
photochemical degradation
Accesso online:https://www.mdpi.com/2304-6740/10/12/252
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