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A cautionary tale of basic azo photoswitching in dichloromethane finally explained

Abstract Many studies of azobenzene photoswitches are carried out in polar aprotic solvents as a first principles characterization of thermal isomerization. Among the most convenient polar aprotic solvents are chlorinated hydrocarbons, such as DCM. However, studies of azobenzene thermal isomerizatio...

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Autori principali: Coral Hillel, Sara Rough, Christopher J. Barrett, William J. Pietro, Ozzy Mermut
Natura: Artigo
Lingua:Inglês
Pubblicazione: Nature Portfolio 2024-11-01
Serie:Communications Chemistry
Accesso online:https://doi.org/10.1038/s42004-024-01321-0
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