Redox-Switchable Behavior of Transition-Metal Complexes Supported by Amino-Decorated N-Heterocyclic Carbenes

The coordination chemistry of the N-heterocyclic carbene ligand IMes^(NMe2)2, derived from the well-known IMes ligand by substitution of the carbenic heterocycle with two dimethylamino groups, was investigated with d⁶ [Mn(I), Fe(II)], d⁸ [Rh(I)], and d¹⁰ [C...

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Autores principales:	Mirko Ruamps, Stéphanie Bastin, Lionel Rechignat, Alix Sournia-Saquet, Laure Vendier, Noël Lugan, Jean-Marie Mouesca, Dmitry A. Valyaev, Vincent Maurel, Vincent César
Formato:	Artigo
Lenguaje:	Inglês
Publicado:	MDPI AG 2022-06-01
Colección:	Molecules
Materias:	redox-active ligands N-heterocyclic carbene organometallic complexes EPR spectroscopy DFT calculations
Acceso en línea:	https://www.mdpi.com/1420-3049/27/12/3776
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