Investigation of solid-state photochemical nitro–nitrito linkage isomerization: crystal structures of trans-bis(ethylenediamine)(isothiocyanato)nitritocobalt(III) salts: thiocyanate, chloride monohydrate, and perchlorate–thiocyanate(0.75/0.25)
The reaction cavities of the nitro groups in the crystals of the title compounds, trans-[Co(NO2)(NCS)(C2H8N2)2]·X, X = SCN− (I), Cl−·H2O (II), and (ClO4−)0.75(SCN−)0.25 (III), have been investigated, revealing that the geometry of the intermolecular N—H...O hydrogen bonds in (I) is unsuitable for ni...
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| Principais autores: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
International Union of Crystallography
2018-10-01
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| coleção: | Acta Crystallographica Section E: Crystallographic Communications |
| Assuntos: | |
| Acesso em linha: | http://scripts.iucr.org/cgi-bin/paper?S2056989018013634 |
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