Unconventional application of the Mitsunobu reaction: Selective flavonolignan dehydration yielding hydnocarpins

Various Mitsunobu conditions were investigated for a series of flavonolignans (silybin A, silybin B, isosilybin A, and silychristin A) to achieve either selective esterification in position C-23 or dehydration in a one-pot reaction yielding the biologically important enantiomers of hydnocarpin D, hy...

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Hlavní autoři:	Guozheng Huang, Simon Schramm, Jörg Heilmann, David Biedermann, Vladimír Křen, Michael Decker
Médium:	Artigo
Jazyk:	Inglês
Vydáno:	Beilstein-Institut 2016-04-01
Edice:	Beilstein Journal of Organic Chemistry
Témata:	dehydration flavonoid hydnocarpin Mitsunobu silybin
On-line přístup:	https://doi.org/10.3762/bjoc.12.66
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