The intriguing modeling of cis–trans selectivity in ruthenium-catalyzed olefin metathesis
In this study we have investigated computationally the origin of the cis–trans selectivity in the Ru-catalyzed cross metathesis (CM) of a prototype monosubstituted olefin, i.e., propene. Our calculations suggest that the origin of the preferential formation of trans-olefins is in the product release...
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| Principais autores: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2011-01-01
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| coleção: | Beilstein Journal of Organic Chemistry |
| Assuntos: | |
| Acesso em linha: | https://doi.org/10.3762/bjoc.7.7 |
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