Probing Methyl Group Tunneling in [(CH₃)₂NH₂][Zn(HCOO)₃] Hybrid Perovskite Using Co²⁺ EPR

At low temperature, methyl groups act as hindered quantum rotors exhibiting rotational quantum tunneling, which is highly sensitive to a local methyl group environment. Recently, we observed this effect using pulsed electron paramagnetic resonance (EPR) in two dimethylammonium-containing hybrid pero...

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Autori principali:	Gediminas Usevičius, Andrea Eggeling, Ignas Pocius, Vidmantas Kalendra, Daniel Klose, Mirosław Mączka, Andreas Pöppl, Jūras Banys, Gunnar Jeschke, Mantas Šimėnas
Natura:	Artigo
Lingua:	Inglês
Pubblicazione:	MDPI AG 2023-01-01
Serie:	Molecules
Soggetti:	methyl group tunneling hybrid perovskite EPR ESEEM
Accesso online:	https://www.mdpi.com/1420-3049/28/3/979
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