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Photochemical Aryl Radical Cyclizations to Give (E)-3-Ylideneoxindoles

(E)-3-Ylideneoxindoles are prepared in methanol in reasonable to good yields, as adducts of photochemical 5-exo-trig of aryl radicals, in contrast to previously reported analogous radical cyclizations initiated by tris(trimethylsilyl)silane and azo-initiators that gave reduced oxindole adducts.

שמור ב:
Principais autores: Michael Gurry, Ingrid Allart-Simon, Patrick McArdle, Stéphane Gérard, Janos Sapi, Fawaz Aldabbagh
פורמט: Artigo
שפה:Inglês
יצא לאור: MDPI AG 2014-09-01
סדרה:Molecules
נושאים:
cyclization
heterocycle
oxindole
UV-light
גישה מקוונת:http://www.mdpi.com/1420-3049/19/10/15891
תגים: הוספת תג
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