Synthesis of silylbut-1-en-3-ynes and buta-1,3-dienes as building blocks via hydrosilylation of 1,4-bis(trimethylsilyl)buta-1,3-diyne

Abstract The selective and efficient synthesis of (E)-1,2,4-trisilylbut-1-en-3-ynes obtained via Pt-catalyzed hydrosilylation of 1,4-bis(trimethylsilyl)buta-1,3-diyne is described. Optimized reaction conditions (Pt(PPh3)4) or Pt2(dvs)3, 100 °C, toluene, 18 h) yielded compounds with high isolation yi...

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Egile Nagusiak:	Kinga Stefanowska-Kątna, Jędrzej Walkowiak, Adrian Franczyk
Formatua:	Artigo
Hizkuntza:	Inglês
Argitaratua:	Nature Portfolio 2024-12-01
Saila:	Scientific Reports
Gaiak:	1,4-Bis(trimethylsilyl)buta-1,3-diyne Hydrosilylation But-1-en-3-ynes 1,3-dienes Building blocks
Sarrera elektronikoa:	https://doi.org/10.1038/s41598-024-82198-w
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