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Selective O‐Acylation of Enol Silyl Ethers with Acyl Fluorides Catalyzed by Fluoride Ions Derived from Potassium Fluoride and 18‐Crown‐6

Abstract The fluoride ion‐catalyzed selective O‐acylation of enol silyl ethers with acyl fluorides using KF and 18‐Crown‐6 is described herein. This catalytic system facilitated the practical and facile reaction of a variety of enol silyl ethers derived from aromatic/aliphatic ketones and aldehydes...

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Principais autores: Prof. Dr. Norio Sakai, Kota Watanabe, Haruka Mori, Yuki Maegawa, Ryuki Takeuchi, Dr. Yohei Ogiwara, Dr. Kento Ishida
Formato: Artigo
Idioma:Inglês
Publicado em: Wiley-VCH 2024-07-01
coleção:ChemistryOpen
Assuntos:
Enol silyl ether
Acyl fluoride
O-Acylation
Vinyl ester
Fluoride ion
Acesso em linha:https://doi.org/10.1002/open.202300300
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