Thermal Rearrangement of Thiocarbonyl-Stabilised Triphenylphosphonium Ylides Leading to (<i>Z</i>)-1-Diphenylphosphino-2-(phenylsulfenyl)alkenes and Their Coordination Chemistry

While thiocarbonyl-stabilised phosphonium ylides generally react upon flash vacuum pyrolysis by the extrusion of Ph₃PS to give alkynes in an analogous way to their carbonyl-stabilised analogues, two examples with a hydrogen atom on the ylidic carbon are found to undergo a quite different...

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Hlavní autoři:	R. Alan Aitken, Graham Dawson, Neil S. Keddie, Helmut Kraus, Heather L. Milton, Alexandra M. Z. Slawin, Joanne Wheatley, J. Derek Woollins
Médium:	Artigo
Jazyk:	Inglês
Vydáno:	MDPI AG 2023-12-01
Edice:	Molecules
Témata:	flash vacuum pyrolysis phosphonium ylide phosphine hemilabile ligand transition metal complex X-ray structure
On-line přístup:	https://www.mdpi.com/1420-3049/29/1/221
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