Selective Generation of Aldimine and Ketimine Tautomers of the Schiff Base Condensates of Amino Acids with Imidazole Aldehydes or of Imidazole Methanamines with Pyruvates—Isomeric Control with 2- vs. 4-Substituted Imidazoles
The Schiff base condensation of 5-methyl-4-imidazole carboxaldehyde, 5Me4ImCHO, and the anion of an amino acid, H<sub>2</sub>N-CH(R)CO<sub>2</sub><sup>−</sup> (R = -CH<sub>3</sub>, -CH(CH<sub>3</sub>)<sub>2</sub> and -CH<sub>2</sub>CH(CH<sub>3</sub>)<sub>2</sub>), gives the aldimine tautomer, Im-CH=...
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| Principais autores: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
MDPI AG
2024-03-01
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| Series: | Molecules |
| Assuntos: | |
| Acceso en liña: | https://www.mdpi.com/1420-3049/29/6/1324 |
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