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Copper(II) Prevents the Saccarine-Dialkylcyanamide Coupling by Forming Mononuclear (Saccharinate)(Dialkylcyanamide)copper(II) Complexes

The reaction in the system Cu<sup>II</sup>/sacNa(H)/NCNR<sub>2</sub> (sacNa(H) = sodium saccharinate (saccharin); R = Me, Et) results in the formation of the complexes [Cu(sac)<sub>2</sub>(NCNR<sub>2</sub>)(H<sub>2</sub>O)<sub>2</sub>] (R = Me <b>1</b>, Et <b>2</b>) instead of the expected products...

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Principais autores: Yulia N. Toikka, Dar’ya V. Spiridonova, Alexander S. Novikov, Nadezhda A. Bokach
Format: Artigo
Sprog:Inglês
Udgivet: MDPI AG 2021-09-01
Serier:Inorganics
Fag:
copper(II) complexes
saccharinate ligand
dialkylcyanamides
X-ray diffraction
computational study
Online adgang:https://www.mdpi.com/2304-6740/9/9/69
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