The role of sulfonate groups and hydrogen bonding in the proton conductivity of two coordination networks

The proton conductivity of two coordination networks, [Mg(H2O)2(H3L)]·H2O and [Pb2(HL)]·H2O (H5L = (H2O3PCH2)2-NCH2-C6H4-SO3H), is investigated by AC impedance spectroscopy. Both materials contain the same phosphonato-sulfonate linker molecule, but have clearly different crystal structures, which ha...

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Detalhes bibliográficos

Principais autores:	Ali Javed, Felix Steinke, Stephan Wöhlbrandt, Hana Bunzen, Norbert Stock, Michael Tiemann
Formato:	Artigo
Idioma:	Inglês
Publicado em:	Beilstein-Institut 2022-05-01
coleção:	Beilstein Journal of Nanotechnology
Assuntos:	coordination network coordination polymer impedance spectroscopy metal-organic framework proton conductivity
Acesso em linha:	https://doi.org/10.3762/bjnano.13.36
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