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Biogenesis of Triterpene Dimers from Orthoquinones Related to Quinonemethides: Theoretical Study on the Reaction Mechanism

The biogenetic origin of triterpene dimers from the Celastraceae family has been proposed as assisted hetero-Diels-Alder reaction (HDA). In this work, computational calculation of HDA between natural quinonemethides (tingenone and isopristimerol) and hypothetical orthoquinones has been performed at...

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Principais autores: Mariana Quesadas-Rojas, Gonzalo J. Mena-Rejón, David Cáceres-Castillo, Gabriel Cuevas, Ramiro F. Quijano-Quiñones
Format: Artigo
Sprog:Inglês
Udgivet: MDPI AG 2016-11-01
Serier:Molecules
Fag:
Celastraceae
quinonemethide
biogenesis
hetero Diels-Alder
DFT
Online adgang:http://www.mdpi.com/1420-3049/21/11/1551
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