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First time exploration and characterization of key-intermediates in palladium-catalysed coupling reactions

Abstract The oxidative addition of a bromoporphyrin onto in situ formed highly active Pd(0) complex allowed us to characterize the Pd(II) intermediate by X-ray crystallography. In addition, after the heterobidentate coordination of Xantphos hemioxide (Xantphos: 4,5-bis(diphenylphosphino)-9,9-dimethy...

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Principais autores: Péter Szuroczki, Attila Bényei, Rafael T. Aroso, Mariette M. Pereira, László Kollár
Formato: Artigo
Idioma:Inglês
Publicado: Nature Portfolio 2026-03-01
Series:Scientific Reports
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Acceso en liña:https://doi.org/10.1038/s41598-026-43634-1
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