Access to cyclopropanes with geminal trifluoromethyl and difluoromethylphosphonate groups
A synthetic route to the bench-stable fluorinated masked carbene reagent diethyl 2-diazo-1,1,3,3,3-pentafluoropropylphosphonate, bearing a trifluoromethyl and a difluoromethyl group is reported for the first time. Its application in CuI-catalyzed cyclopropanation reactions with aromatic and aliphati...
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| Principais autores: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2023-04-01
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| coleção: | Beilstein Journal of Organic Chemistry |
| Assuntos: | |
| Acesso em linha: | https://doi.org/10.3762/bjoc.19.39 |
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