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Examining the effects of additives and precursors on the reactivity of rhodium alkyl nitrenes generated from substituted hydroxylamines

In this study, the reactivity of the alkyl nitrenes, generated from the substituted hydroxylamine precursors, was determined using the same rhodium catalyst. The results revealed that in competitive C–H insertion experiments, the regioselectivity between benzylic and tertiary C–H bonds could be modu...

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Библиографические подробности
Главные авторы: Hidetoshi Noda, Yasuko Asada, Masakatsu Shibasaki
Формат: Artigo
Язык:Inglês
Опубликовано: Frontiers Media S.A. 2023-11-01
Серии:Frontiers in Chemistry
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Online-ссылка:https://www.frontiersin.org/articles/10.3389/fchem.2023.1271896/full
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