Preparation of Oxysterols by C–H Oxidation of Dibromocholestane with Ru(Bpga) Catalyst

Seven mono- and dihydroxycholesterols were prepared by direct C–H oxidation of the cholestane skeleton with a recently developed Ru(Bpga) catalyst (Ru(Bpga) = [RuCl (bpga) (PPh₃)] Cl; bpga = 2-(bis(pyridin-2-ylmethyl)amino)-<i>N</i>-(2,6-dimethylphenyl)acetamide)). Due to the high selecti...

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Auteurs principaux:	Yui Fujii, Makoto Yoritate, Kana Makino, Kazunobu Igawa, Daiki Takeda, Daiki Doiuchi, Katsuhiko Tomooka, Tatsuya Uchida, Go Hirai
Format:	Artigo
Langue:	Inglês
Publié:	MDPI AG 2021-12-01
Collection:	Molecules
Sujets:	cholesterol oxysterol C–H oxidation Ru (bpga) 25-hydroxycholesterol dihydroxycholesterol
Accès en ligne:	https://www.mdpi.com/1420-3049/27/1/225
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