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Crystal-field splitting strength of U-6d orbitals in NaUO3, KUO3 and RbUO3

Here, the uranium valence electronic structures in the perovskite-based ternary uranate systems NaUO3, KUO3 and RbUO3 are reported on the basis of high-energy resolved fluorescence-detected X-ray absorption spectroscopy experiments at the U L3 edge and relativistic quantum chemistry calculations bas...

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Principais autores: Simon Orlat, Igor Prozheev, Ine Arts, Gregory Leinders, Elena Bazarkina, Kristina Kvashnina, Filip Tuomisto, Philippe Martin, Philippe Moisy, René Bes
Formato: Artigo
Idioma:Inglês
Publicado: International Union of Crystallography 2025-09-01
Series:Journal of Synchrotron Radiation
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Acceso en liña:https://journals.iucr.org/paper?S1600577525005156
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