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Thermodynamic characterization of the dimerization equilibrium of newly synthesized polymethine cyanine dyes

The monomer–dimer equilibrium and thermodynamics of three new cyanine dyes were investigated by spectrophotometric and chemometric methods. The dimerization constants of these new cyanine dyes were determined by studying the dependence of their absorption spectra on the temperature in the range 25–8...

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Principais autores: MIKAEL KUBISTA, TODOR G. DELIGEORGIEV, FERESHTEH SHIRI, JAHAN B. GHASEMI
Formato: Artigo
Idioma:Inglês
Publicado em: Serbian Chemical Society 2008-10-01
coleção:Journal of the Serbian Chemical Society
Assuntos:
chemometrics
dimerization
cyanine dyes
absorption titration
enthalpy
entropy
Acesso em linha:http://www.shd.org.rs/JSCS/Vol73/No10/JSCS-3782.pdf
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