Asymmetrische Katalyse durch Vitamin B12: Isomerisierung achiraler 1,4-Epiperoxide zu optisch aktiven 4-Hydroxycycloalk-2-en-1-onen
Achiral cyclic 1,4-epiperoxides undergo fast isomerization to optically active 4-hydroxycycloalk-2-en-1-ones in presence of catalytic amounts of cob(II)alamin (B12r). Light-induced oxygenation of cyclic conjugated dienes in MeOH to 1,4-epiperoxides followed by isomerization with 0,5 mol-%...
Gorde:
| Egile Nagusiak: | , |
|---|---|
| Formatua: | Artigo |
| Hizkuntza: | Alemão |
| Argitaratua: |
Swiss Chemical Society
1991-01-01
|
| Saila: | CHIMIA |
| Sarrera elektronikoa: | https://www.chimia.ch/chimia/article/view/1991 |
| Etiketak: |
Etiketarik gabe, Izan zaitez lehena erregistro honi etiketa jartzen!
|