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Enzymatic Kinetic Resolution of tert-Butyl 2-(1-Hydroxyethyl)phenylcarbamate, A Key Intermediate to Chiral Organoselenanes and Organotelluranes

The enzymatic kinetic resolution of tert-butyl 2-(1-hydroxyethyl) phenylcarbamate via lipase-catalyzed transesterification reaction was studied. We investigated several reaction conditions and the carbamate was resolved by Candida antarctica lipase B (CAL-B), leading to the optically pure (R)- and (...

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Detalhes bibliográficos
Principais autores: Leandro Piovan, Monica D. Pasquini, Leandro H. Andrade
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI AG 2011-09-01
coleção:Molecules
Assuntos:
Acesso em linha:http://www.mdpi.com/1420-3049/16/9/8098/
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