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Electrochemical Synthesis of Benzo[b]Phosphole Oxides via Dehydrogenative Annulation Using 1,4‐Diazabicyclo [2.2.2]Octane as a Mediator

The electrochemical intermolecular annulation of diarylphosphine oxides with alkynes for the synthesis of benzo[b]phosphole oxides has been reported. The reaction proceeded under transition‐metal‐ and oxidant‐free conditions via indirect electrolysis, using 1,4‐diazabicyclo[2.2.2]octane as a mediato...

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Principais autores: Koichi Mitsudo, Sakura Kinjo, Yasuyuki Okumura, Eisuke Sato, Riki Kato, Yuta Nishina, Seiji Suga
פורמט: Artigo
שפה:Inglês
יצא לאור: Wiley-VCH 2026-04-01
סדרה:ChemElectroChem
נושאים:
annulation
benzophosphole oxide
electrochemistry
hydrogen atom transfer
radical cyclization
גישה מקוונת:https://doi.org/10.1002/celc.70175
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