Mechanisms of Sulfoxidation and Epoxidation Mediated by Iron(III)-Iodosylbenzene Adduct: Electron-Transfer vs. Oxygen-Transfer Mechanism

The mechanisms of sulfoxidation and epoxidation mediated by previously synthesized and characterized iron(III)-iodosylbenzene adduct, Fe^III(OIPh) were investigated using para-substituted thioanisole and styrene derivatives as model substrates. Based on detailed kinetic reaction experiment...

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Prif Awduron:	Patrik Török, Dóra Lakk-Bogáth, József Kaizer
Fformat:	Artigo
Iaith:	Inglês
Cyhoeddwyd:	MDPI AG 2023-06-01
Cyfres:	Molecules
Pynciau:	non-heme models iron(III)-iodosylarene complex sulfoxidation epoxidation O-atom transfer kinetics
Mynediad Ar-lein:	https://www.mdpi.com/1420-3049/28/12/4745
Tagiau:	Ychwanegu Tag Dim Tagiau, Byddwch y cyntaf i dagio'r cofnod hwn!