Mechanochemistry Drives Alkene Difunctionalization via Radical Ligand Transfer and Electron Catalysis

Abstract A general and modular protocol is reported for olefin difunctionalization through mechanochemistry, facilitated by cooperative radical ligand transfer (RLT) and electron catalysis. Utilizing mechanochemical force and catalytic amounts of 2,2,6,6‐tetramethylpiperidinyloxyl (TEMPO), ferric ni...

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Hlavní autoři:	Subrata Patra, Bhargav N. Nandasana, Vasiliki Valsamidou, Dmitry Katayev
Médium:	Artigo
Jazyk:	Inglês
Vydáno:	Wiley 2024-08-01
Edice:	Advanced Science
Témata:	electron catalysis mechanochemistry nitration olefin difunctionalization radical ligand transfer (RLT)
On-line přístup:	https://doi.org/10.1002/advs.202402970
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