Photoinduced radical generation and trapping by acrylonitrile of N-Boc secondary amine and N-Boc N-methyl α-amino acid ester at α-position using two-molecule photoredox catalysts

The photoreaction of an N-Boc secondary amine and N-Boc N-methyl α-amino acid ester with acrylonitrile using inexpensive two-molecule photoredox catalysts results in the production of α-alkylated amine through the generation of an α-carbamy radical under mild conditions. In particular, this mothed l...

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Autors principals:	Shoki Nagaya, Hibiki Miyagawa, Ryoga Hashimoto, Toshiki Furutani, Mugen Yamawaki, Hirotsugu Suzuki, Toshio Morita, Yasuharu Yoshimi
Format:	Artigo
Idioma:	Inglês
Publicat:	Elsevier 2023-12-01
Col·lecció:	Journal of Photochemistry and Photobiology
Matèries:	Two-molecule photoredox catalyst Oxidation of N-Boc secondary amine Radical cation of N-Boc secondary amine N-Boc N-methyl α-amino acid ester Generation of α-carbamyl radical
Accés en línia:	http://www.sciencedirect.com/science/article/pii/S2666469023000490
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