Actinide‐Pnictide Chemistry: A Uranium Primary Alkyl Stibinide and a Diuranium Hexaantimonide‐Tetralithium Zintl Cluster

Abstract Structurally characterised U−Sb bonds are rare. Here, the synthesis and characterisation of [U(TrenDMBS){Sb(H)C(H)(SiMe3)2}] (5, TrenDMBS=N(CH2CH2NSiMe2But)3) and [{U(TrenTIPS)}2{Sb3(μ6‐Li)(μ‐Li[THF]2)3Sb3}] (6, TrenTIPS=N(CH2CH2NSiPri3)3) are reported. Complex 5 is an unprecedented primary...

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Auteurs principaux:	Dr. Thomas M. Rookes, Dr. Gábor Balázs, Dr. Benedict M. Gardner, Dr. Ashley J. Wooles, Prof. Dr. Manfred Scheer, Prof. Dr. Stephen T. Liddle
Format:	Artigo
Langue:	Inglês
Publié:	Wiley-VCH 2023-11-01
Collection:	ChemistryEurope
Sujets:	antimony antimonide stibinide uranium Zintl cluster
Accès en ligne:	https://doi.org/10.1002/ceur.202300067
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