Photochemical and Beckmann rearrangement of (Z)-cholest-4-en-6-one oxime
Beckmann rearrangement of (Z)-cholest-4-en-6-one oxime (4) (prepared in 4 steps starting from cholest-5-en-3b-ol (1)) with thionyl chloride in dioxane solution afforded an enamide-type lactam, i.e., 7-aza-B-homocholest-4-en-6-one (6) as a single product. Photoreaction of the same compound in methano...
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| Autores principales: | , , , , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
Serbian Chemical Society
2004-06-01
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| Colección: | Journal of the Serbian Chemical Society |
| Materias: | |
| Acceso en línea: | http://www.shd.org.yu/HtDocs/SHD/Vol69/No6/V69-No6-01.pdf |
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