Rhodium-catalyzed enantioselective and diastereodivergent access to diaxially chiral heterocycles
Abstract N-N axially chiral biaryls represent a rarely explored class of atropisomers. Reported herein is construction of diverse classes of diaxially chiral biaryls containing N-N and C-N/C-C diaxes in distal positions in excellent enantioselectivity and diastereoselectivity. The N-N chiral axis in...
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| Principais autores: | , , , , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Nature Portfolio
2023-08-01
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| Serier: | Nature Communications |
| Online adgang: | https://doi.org/10.1038/s41467-023-39968-3 |
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